Water based removable paint formulation and system

ABSTRACT

An easily removable coating or paint which is a formulation of acrylic acid polymers and a urethane polymer preferably two acrylic acid polymers are used, one with a relatively high acid number and hardness temperature (glass transition) (Tg) and the other with a lower acid number and hardness temperature (Tg). This removable paint is applied to a surface by roller, screen printing, spraying or brushing and can be removed by a remover which is basically an alkali material with a surfactant. The remover needs to be agitated and allowed to set for a few minutes and then washed away with water. Ammonium hydroxide with surfactant and acrylic thickeners in water is one remover. Another remover is a combination of more than one alkalis, solvent, surfactants and thickeners.

CROSS-REFERENCE TO RELATED APPLICATION

This application claims priority to copending U.S. provisionalapplication entitled, “A WATER BASED REMOVABLE PAINT FORMULATION ANDSYSTEM” having Ser. No. 60/736,421, filed Nov. 14, 2005 which isentirely incorporated herein by reference.

TECHNICAL FIELD

The invention is for a removable paint or coating, a paint remover forremoving the paint or coating, a system for a removable coating andremoving of the coating and a method for coating or painting the hard orsealed surface of articles, floors and roads and removing the coating orpaint. The paint composition can be used to provide a removable paint toa highway which can be readily removed when needed.

BACKGROUND OF THE INVENTION

It is many times desirable to have a removable paint formulation thatcan be applied over a hard surface or over another paint andsubsequently removed without damaging the underlying surface or paint.This is difficult to accomplish because the solvents that will removethe removable paint that it is intended to remove may also remove theunderlying paint or damage its luster or pose environmental or firehazards. A removable paint would be desirable for automobile signs, andremovable colors on surfaces, such as floors and other hard or sealedsurfaces and movie sets. A removable paint that could be applied tohighway surfaces, such as concrete or asphalt, is especially desirable.The paint would need to withstand the wear and temperature extremesexperienced on highway surfaces, but be easily removable during thosesurface extreme conditions and under normal conditions.

There is also a need for temporary protective coating or paint forequipment or vehicles that are exposed to the environment. Such acoating or paint which can be applied quickly with little effort, isresistant to environmental damage and can be removed easily afterweathering for an extended period.

SUMMARY OF THE INVENTION

An easily removable durable paint or coating and a paint remover forremoving the paint is provided by this invention. The removable paint isa dispersion of a balanced formulation of acrylic polymers and aurethane polymer. The combination is neutralized with an alkali.Ammonium hydroxide is preferred. From 19 to 34% (based on dry solidsweight) of the dispersion is an acrylic polymer, with 0.2 to 4% of aurethane polymer and 0.06 to 0.6% (based on dry weight) of an alkali andthe balance is water. These percentages are based on the dry weight ofingredients. Preferably from 22 to 30% of the formulation is the acrylicpolymer and the urethane polymer is present in an amount from 0.4 to1.2% and ammonium hydroxide is present in an amount of 0.06 to 0.3%, allof these percentages being by dry weight in the formulation. Excellentresults are obtained when the acrylic polymer is present in an amount ofapproximately 26% by dry weight and the urethane polymer is present inan amount of approximately 0.7% by dry weight and the ammonium hydroxideis present in an amount of about 0.28% by dry weight.

It is preferred to use a combination of acrylic polymers in which 19 to26% of the formulation is of an acrylic polymer with an acid numberbetween 60 and 70 and a hardness temperature (glass transitiontemperature) (Tg) of between 26° C. and 30° C. and 2.4% to 6.0% byweight of an acrylic polymer with an acid number between 28 and 34 and ahardness temperature (Tg) of between 22° C. and 26° C. Preferably theurethane polymer dispersion has a viscosity (cP) of from 120 to 130 anda pH of 8+/−1.5 and the urethane is present in an amount of from 0.4 to1.2% by weight. The proportion between the acrylic polymers can beadjusted to achieve the desired characteristics of the paint and theamount of acrylic polymer present can be adjusted in relationship to theurethane polymer to achieve the desired characteristics.

Pigment or dyes can be added to the mixture to make the coating a paint.Effect particles, such as reflective beads can be added to the mixtureto provide reflective qualities which is especially important inapplications to highways and airports. Various other effects can beachieved, such as by addition of iridescent pearl pigment or ultravioletlight reflective pigments.

The removable paints and coatings of this invention can be removed bycontact with alkaline solutions that contain a surfactant. A preferredremover solution comprises 1 to 5% ammonium hydroxide, 2 to 5% of alkalithickeners and the balance water. The remover solution is applied to thecoating or paint and brushed or otherwise agitated and allowed to setfor a few minutes and then removed by water. Another type of removercomposition is a combination of dibasic esters and thickeners.

DETAILED DESCRIPTION OF THE INVENTION

An easily removable coating or paint is provided by this invention. Apaint remover is provided for removing the paint or coating under normalconditions. A paint remover for removing the paint from a surface thatis very hot, such as a highway in the summertime, is also provided. Theremover breaks up the paint and allows the water dispersion of theresidue, which may be collected to prevent damage to the environment.

The removable paint is a carefully balanced formulation of acrylicpolymers and a urethane polymer. Acrylic polymeric colloidal dispersionssuch Carboset® 514-H, manufactured by Noveon, Inc., are used in thewater-based removable coatings and paints of the present invention. Thisdispersion has 40% weight total solids and is supplied in ammonia waterand has a pH of between 6.6 and 7.4. The Carboset® 514-H has arelatively high acid number of about 65 and hardness temperature (glasstransition) (Tg) of about 28° C.

Preferably another acrylic polymeric colloidal dispersion is also usedto obtain the correct balance of hardness and acidity. The Carboset® 519dispersion has 40% weight total solids and has been found to be useful.Carboset® 519 has lower acid number of about 32 and hardness temperature(Tg) of 24° C., and a pH of between 7.9 and 8.7. The combined effect ofthe properties of these two acrylic polymers provides the right degreeof adhesion, alkali resistance, flexibility, hardness and surface tackof the film. This combination is especially useful to permit the easyremoval of the coating or paint but yet insure adequate adhesion andhardness prior to removal. The combination of the Carboset® 514-H and519 is especially important because the dried film of the 514-H is morereadily dissolved by alkalis compared to the 519 because the 514-H has ahigher acid number. Thus when an alkali based remover composition isapplied to the coating of this invention it will start dissolving the514-H component of the coating first and then proceed on to dissolvingthe 519 and allowing the coating to be removed from the surface.

The acrylic polymers can be neutralized by caustic soda, caustic potash,amines, alkanol amines or ammonia. Ammonia is preferred.

A polyurethane is included in the coating or paint. Polyurethaneprovides a surface hardness as well as flexibility giving the paint orcoating a high abrasion and scuff resistance. The preferred polyurethaneis Sancure® 815, which is manufactured by Noveon, Inc. as a dispersionof 35% weight total solids, and has a viscosity (cP) of about 125 with apH of 8+/−1. It has a gloss at a 60° angle of 87 and a Sward hardness of70. The properties of alkali resistance, adhesion, flexibility, surfacehardness and tackiness can be balanced by adjusting the amount ofCarboset® 514, 519 and polyurethane in the formulation. The Sancure® 815provides a film that is hard, glossy but flexible and with a hightensile strength which improves the quality of the coating or paint. TheSancure® 815 has a high abrasion resistance and a high resistance toalkali and detergent. A small quantity of the Sancure® 815 gives thefinal coating the necessary hardness and resistance which is especiallyimportant for use on highways.

Pigment can be added to the coating formulation to make a paint.Typically, pigment in an amount of from 6 to 22% by weight of theformulation to be sprayed or brushed on a surface is added depending onthe pigment color and other factors.

The coating or paint (not including the pigment) of this invention canalso include optional ingredients such as preservatives, biocides,thickeners, special effects additives and the like. Proxel GXL hasproven to be a good preservative and biocide. These additionalingredients are not critical to the function of the coating or the paintbut aid in improving the commercial utility and have other advantages.

A dispersion of a coating or paint (not including the pigment) of thepresent invention preferably comprises:

COMPONENT % BY DRY WEIGHT Acrylic polymer or co-polymer 19-34Polyurethane 0.2-4   Ammonium hydroxide 0.06-0.6 (active content) WaterBalance

A dispersion of a preferred coating or paint (not including the pigment)composition comprises:

COMPONENT % BY DRY WEIGHT Acrylic polymer or co-polymer 22-30Polyurethane 0.4-1.2 Ammonium hydroxide 0.06-0.3 (active content) WaterBalance

A mixture of acrylic polymers provides the optimum characteristics forthe coating. It has been found that a dispersion of from 19 to 26% (byweight of dry solids) of an acrylic polymer with an acid number ofbetween 60 and 70 and a hardness temperature (Tg) of between 26° C. and30° C. mixed with 2.4 to 6% (by weight of dry solids) of an acrylicpolymer with an acid number of between 28 and 34 and a hardnesstemperature (Tg) of between 22° C. and 26° C. results in a good balanceof the acrylic polymers. This is preferably mixed with from 0.4 to 1.2%(by weight of dry solids) of a urethane polymer with a viscosity (cP) of120 to 130 and pH of 8+1-1.5 to achieve a good balance of thecharacteristics of scuff resistance, surface hardness and ease ofremoval with a remover formulation.

It is important that the mixture of the acrylic polymers andpolyurethane be carefully balanced. The acrylic polymer with a high acidnumber has a large number of carboxyl groups which react with thehydroxyl groups provided by the ammonium hydroxide and other sourcesfacilitating the removal of the coating by the remover composition. Onthe other hand the acrylic polymer with the low acid number has fewercarboxyl groups and are more resistant to attack by hydroxyl groupswhich helps preserve the stability of the coating. Having acrylicpolymers with different hardness numbers is also balanced to make surethe coating has sufficient hardness to stand general use but can beeasily removed by the remover compositions. The polyurethane provides ahard surface and resistance to attack by hydroxyl groups. Molecules ofthe acrylic and urethane polymers are intermixed throughout the coatingwhich provides the delicate balance between hardness and amorphousstates, resistance to attack and ease of removal by hydroxyl groups.This balance is achieved by a formulation that contains approximatelyabout 22% (by dry weight) of Carboset 514-H, 4% (by dry weight) Carboset519 and 0.7% (by dry weight) Sancure 815 and 0.3% (by dry weight)ammonium hydroxide.

The coating or paint of this invention is prepared by mixing the acrylicdispersions and the polyurethane dispersions with water and adjustingthe pH to between 8 and 8.5 preferably using ammonium hydroxide.Additional water is then added. A pigment may be added to the coating ifa colored surface is desired.

Increasing the amount of polyurethane in the paint or coating increasesthe alkali resistance and surface hardness, but makes the coating orpaint more difficult to remove. The same effect can also be obtained byincreasing the amount of the acrylic component with the lower acidicvalue (Carboset® 519), which makes the coating or paint more difficultto remove. The correct amount of water must be used in the dispersion.

Pigment can be added to the mixture to make a paint in the normalmanner. The water content can be adjusted for the water content of thepigment dispersion. Special effect particles can be added to addtexture, or reflection characteristics to the coating or paint in thenormal manner. Retro-reflector beads can be added to the paint as it isbeing applied to roadways and airports to provide reflective characterto the paint. Infrared absorbers and reflectors and surface frictionmodifiers can also be included.

The removable paints of this invention have sufficient adhesion anddurability as to be used as a permanent paint if desired. Thus, thepaint of this invention can be either permanent or temporary, asdesired. This removable paint has the unique ability to heal or regainits adhesion to the surface it is applied to. The characteristic isreferred to as “creeping,” which enables the removable paint to have alonger life span, which is especially useful in extending the highreflectivity and long life of any retro-reflected beads applied to thepaint.

The paint or coating is applied to a surface by spraying, brushing,curtain coating, wire wound rod, rolling or any other satisfactorymethod of applying a coating or a paint to a surface. This paint orcoating works best on surfaces that are hard and smooth or have beensealed in order to make the removal of the paint complete. Otherwise,some of the paint may be lodged in the pores of the surface making itdifficult to remove. More intensive scrubbing or the use of a pressurewasher with the remover solution will achieve a total removal of thepaint in such cases.

Remover Composition

Basically the removable paints and coatings of this invention can beremoved by contact with alkaline solutions that have a surfactant. Thealkalis react with the carboxylic acid groups to form an acrylic saltwhich causes a chain extension of the acrylic polymers and dissolutionof the film. From 0.2 to 5% by weight of an alkali and thickener isused. Preferably the remover solution consists of ammonium hydroxide,ammonium carbonate, and a surfactant. These remover compositions arebrought into contact with the removable paint for a few minutes andagitated by a sponge, mop or brush and then washed away with water.Other alkalis can be substituted for the ammonium hydroxide to reducethe objectionable odor of ammonia.

A preferred remover solution comprises:

COMPONENT % BY WEIGHT Ammonium hydroxide 1 to 5 Alkali Thickeners 2 to 5Water balance

An acrylic polymer thickener may be used with this remover solution. Asmall amount of ammonium carbonate that is less than 0.5% by weight mayalso be used. Ethoxylated caster oil may also be used in an amount from0.1 to 1% by weight. This remover solution preferably has a pH of from11.5 to 12.5. The pH of the diluted solution is from 8.0 to 9.0.

In the event the paint has been applied to a surface that may be at ahigh temperature when it is desired to remove the paint, a proprietarymixture composed of organic solvents may be added to the remover. Apreferred proprietary mixture is composed of 2-butoxy ethanol,nonylphenol ethoxylate, sodium metasilicate pentahydrate,monoethanolomine and isopropryl alcohol. Preferably the proprietarymixture is added in an amount from 20 to 80% by weight of the solution.An alkali thickener such as an acrylic polymer may be added to thismixture. Preferably the thickeners are added in an amount of from 3 to7% by weight. Ammonium hydroxide is not necessary with this remover, asthe monoethanolamine from the proprietary mixture provides the necessaryalkalinity. A small amount of ammonium carbonate may also be added toproduce this remover solution. It may be used in an amount of 0.05 to0.2% by weight as needed to obtain the necessary pH for the removersolution. The proprietary mixture is preferably added to the aboveremover solution at the end of mixing the regular remover solution. Thisremover can also be applied by spraying or brushing onto the surface andagitating by a sponge, brush or mop and allowing to set a few minutesand then washing away with water. It will be necessary to not allow anyof this residue to escape into the environment. The residue may becollected by a vacuum or other collection means.

Another type of remover composition is a combination of dibasic estersand thickeners. The dibasic esters may be derived from adipic acid,glutaric acid or succinic acid. A thickening agent is used to stabilizethe ester water emulsion and provide good flow control. Thickeningagents that are preferred include various gums such as xanthan,polyvinyl alcohol and clay derivatives. A surfactant is preferably usedwith this remover composition.

In some cases the remover composition must be formulated to avoiddamaging the surface to which the removable paint or coating is applied.A satisfactory composition for achieving these results is a combinationof D-limonene and a dibasic acid ester and N-methyl pyrrolidone.

Any of these remover compositions can contain optional ingredients, suchas surfactants, defoamers, corrosion inhibitors, biocides andthickeners. The remover is preferably sprayed on the paint and scrubbedwith a brush, allowed to set for a few minutes and washed away withwater.

It should be emphasized that the above-described embodiments of thepresent invention are merely possible examples of implementations,merely set forth for a clear understanding of the principles of theinvention. Many variations and modifications may be made to theabove-described embodiment(s) of the invention without departingsubstantially from the spirit and principles of the invention. All suchmodifications and variations are intended to be included herein withinthe scope of this disclosure and the present invention and protected bythe following claims.

The present invention is described more specifically with reference tothe following examples.

Example 1

A coating formulation was prepared from the components set forth inTable I. All of the components set forth in Table 1 except for thePROXEL were placed in a slow speed mixer and mixed together. The PROXELGXL was diluted in water and then added to the mixture.

TABLE I NAME OF COMPONENT % BY WEIGHT WEIGHT GRAMS Carboset ® 514Hmanufactured 81.46 21630.72 by Noveon, Inc. Carboset ® 519 manufactured15.02 3988.48 by Noveon, Inc. Sancure ® 815 manufactured 2.81 745.92 byNoveon, Inc. Proxel GXL manufactured by 0.05 14.00 Zeneca Corp. Water(filtered and sterilized) 0.66 174.00 Total 100.0% 2653.12 TheCarboset ® 514-H is an aqueous acrylic colloidal dispersion in which theacrylic has an acid number of about 65 and a hardness temperature (Tg)of about 28° C. The Carboset ® 519 is also an aqueous acrylic colloidaldispersion in which the acrylic has an acid number of about 32 and atemperature number (Tg) of about 24° C. The Sancure ® 815 is an aqueousaliphatic urethane polymer dispersion. The Proxel GXL is a preservativeand biocide.

The formulation obtained by mixing the ingredients in Table I is thenmixed with ammonium hydroxide and water to achieve a final formulationset forth in Table II. The ammonium hydroxide is a solution of ammoniain water in which the anhydrous ammonia was present in an amount of 28%by weight. The pH of the final formulation was adjusted to between 8.0and 8.5 by the use of ammonium hydroxide.

Desired pigments or dyes may be added to the mixture. The coating orpaint formulation set forth was applied to a surface to be painted byspraying.

TABLE II NAME OF COMPONENT % BY WEIGHT Carboset 514-H 55.1 Carboset 51910.16 Sancure 815 1.9 Proxel GXL 0.04 Ammonium hydroxide (28%) 0.98Water 31.83 Total 100%

Example 2

A remover was prepared by mixing all of the ingredients set forth inTable III together. The liquids were mixed first and then the thickenerswere added. The ammonium carbonate and ammonium hydroxide were thenadded.

TABLE III NAME OF COMPONENT % BY WEIGHT WEIGHT IN GRAMS Water(sterilized) 94.34 17632.00 Ethoxylated Castor Oil, Trylox 5909 0.5196.15 Carbazol violet pigment 0.05 10.00 Fragrance: Grape type 0.62116.00 Acrylic polymer thickener, Acrysol TT-935 2.67 499.20Manufactured by Rohm & Haas Acrylic polymer thickener, Carbopol EZ-30.61 113.52 Manufactured by Noveon, Inc. Ammonium Carbonate 0.11 20.00Ammonium Hydroxide (28%) 1.09 203.00 100% 18698.87

The remover prepared in accordance with the formula in Table III wassprayed and brushed on the surface coated with the coating prepared inaccordance with the formula set forth in Table I. The remover solutionwas agitated on the surface and allowed to set for 6 minutes and thenthe remover solution and the removable coating were washed away by waterleaving an uncoated surface.

Example 3

The coating prepared in accordance with Example 1 was coated on asurface and removed with a remover prepared in accordance with a removerhaving a formulation set forth in Table IV.

TABLE IV NAME OF COMPONENT % BY WEIGHT WEIGHT IN GRAMS Water(sterilized) 33.31 6029.00 Carbazol violet pigment 0.06 10.00 Fragrance:Grape type 0.96 174.00 Acrylic polymer thickener, Acrysol TT-935 3.45624.00 Manufactured by Rohm & Haas Acrylic polymer thickener, CarbopolEZ-3 0.63 113.52 Manufactured by Noveon, Inc. Proprietary Mixture 61.49Manufactured by Pro Force 11130.00 Ammonium Carbonate 0.11 20.00 Total100% 18100.52

The proprietary mixture in Table IV is composed of 2-butoxy ethanol,nonylphenol ethoxylate, sodium metasilicate pentahydrate,monoethanolomine and isopropyl alcohol. This remover was prepared bymixing all of the ingredients as described in Example 2 and then addingthe described proprietary mixture at the end of the mixing cycle. Thisremover was sprayed onto the surface and brushed and allowed to set fora few minutes and then washed away with water and collected in acollection chamber.

Example 4

A coating prepared in accordance with Example 1 was sprayed on aconcrete surface and removed with a remover of the formulation of TableV. The remover was sprayed on the concrete and brushed and allowed toset for several minutes and washed away with water along with thecoating and collected in a collection chamber.

TABLE V REMOVER FORMULATION MATERIAL % BY WEIGHT Water 53.04 Isopropanol6.00 Ethylene glycol monobutyl ether, 10.00 Glycol Ether EB sold byEquistar Chemicals, LP Acrylic polymer thickener, 0.60 Carbopol EZ-3manufactured by Noveon, Inc. Surfactant, that is a mixture 18.00 oflinear secondary alcohols reacted with ethylene oxide, Tergitol 15-S-7,manufactured by Union Carbide Corp. Monoethanolamine 10.00 Wacker ®Silicone SE 21 (10%) 0.24 As an antifoamer Potassium silicate solution1.7 sold as Kasil ® KOH 45% 0.38 Purple Dye S-578 .04 Total 100.00

The remover was prepared by heating water in a tank via a steam spargeto a temperature of approximately 120 to 140° F. while being agitated ata slow speed. The isopropanol and Glycol Ether EB were then added andmixed for 5 minutes. The Carbopol EZ-3 was then sifted in very slowlyand the agitation increased to disperse and dissolve. The mixingincluded until the Carbopol EZ 3 was dissolved. The Tergitol 15-S-7 andmonoethanolamine, Wacker® silicone SE 21 and KASIL was added and mixedfor 15 minutes. The KOH was then added very slowly in a precise amount.The dye was then added and mixed for 30 minutes. The specifications forthe remover are set forth below.

QC Specifications

Test Range Color Dark Purple Appearance Hazy, Viscous Liquid pH 11.5 to12.5 Specific Gravity 1.120 to 1.128 Viscosity, cPs 5/30 500 to 1500 cPsRefractometer (1:1) 19 to 21

1. A weather resistant, rapidly removable, removable coating compositionwhich comprises: a. from about 19 to about 34% by weight of an acrylicpolymer; b. from about 0.2 to 4% by weight of an aliphatic water-borneurethane polymer; and c. from 0.06 to 0.6% by weight of an alkali. 2.The composition of claim 1, wherein the acrylic polymer is present in anamount of from about 22 to 30% by weight and the aliphatic water-borneurethane polymer is present in an amount from about 0.4 to 1.2% byweight and the alkali is ammonium hydroxide which is present in anamount from 0.06 to 0.3% by weight.
 3. The composition of claim 1,wherein the acrylic polymer is present in an amount of approximately 26%by weight and the aliphatic water-borne urethane polymer is present inan amount of approximately 0.7% by weight and the alkali is ammoniumhydroxide which is present in an amount of approximately 0.28% byweight.
 4. The composition of claim 1, wherein the acrylic polymer (a)comprises 19 to 26% by weight of an acrylic polymer with an acid numberof between 60 and 70 and a hardness temperature (Tg) of between 26° C.and 30° C. and 2.4 to 6% by weight of an acrylic polymer with an acidnumber of between 28 and 34 and a hardness temperature (Tg) of between22° C. and 26° C. and the aliphatic water-borne urethane polymer (b) ispresent in an amount of from 0.4 to 1.2% by weight and this urethanepolymer has a viscosity (cP) of from 120 to 130 and a pH of 8+/−1.5 andthe alkali (c) is ammonium hydroxide present in an amount of from 0.06to 0.6% by weight to achieve a pH of the composition of from 8 to 8.5pH.
 5. The composition of claim 1, in which the acrylic polymer (a)comprises approximately 22% by weight of an acrylic polymer having anacid number of approximately 65 and a hardness temperature (Tg) of 28°C. and approximately 4% by weight of an acrylic polymer with an acidnumber of approximately 32 and a hardness temperature (Tg) of 24° C. anda urethane polymer (b) has a viscosity (cP) of approximately 125 and apH of 8+/−1 and is present in an amount of approximately 0.7% by weightand the alkali (c) is ammonium hydroxide that is present in an amount of0.06 to 0.6% by weight as needed to achieve a pH of the compositionbetween 8 and 8.5.
 6. The composition of claim 1 to which a dispersiblepigment has been added in amount to achieve the desired color of paint.7.-9. (canceled)
 10. A method for temporarily protecting the surface ofunpainted or painted articles which comprises coating the surface of thearticle with the composition of claim
 1. 11. A method of claim 10 inwhich the acrylic polymer in the composition is present in an amount offrom about 22 to 30% by weight and the aliphatic water-borne urethanepolymer is present in an amount from about 0.4 to 1.2% by weight and thealkali is ammonium hydroxide which is present in an amount from 0.06 to0.3% by weight.
 12. The method of claim 10 in which the acrylic polymerin the composition is present in an amount of approximately 26% byweight and the aliphatic water-borne urethane polymer is present in anamount of approximately 0.7% by weight and the alkali is ammoniumhydroxide which is present in an amount of approximately 0.28% byweight.
 13. The method of claim 10 in which the acrylic polymer (a) inthe composition comprises 19 to 26% by weight of an acrylic polymer withan acid number of between 60 and 70 and a hardness temperature (Tg) ofbetween 26° C. and 30° C. and 2.4 to 6% by weight of an acrylic polymerwith an acid number of between 28 and 34 and a hardness temperature (Tg)of between 22° C. and 26° C. and the aliphatic water-borne urethanepolymer (b) is present in an amount of from 0.4 to 1.2% by weight andthis urethane polymer has a viscosity (cP) of from 120 to 130 and a pHof 8+/−1.5 and the alkali (c) is ammonium hydroxide present in an amountof from 0.06 to 0.6% by weight to achieve a pH of the composition offrom 8 to 8.5 pH.
 14. The method of claim 10 in which the acrylicpolymer (a) in the composition comprises approximately 22% by weight ofan acrylic polymer having an acid number of approximately 65 and ahardness temperature (Tg) of 28° C. and approximately 4% by weight of anacrylic polymer with an acid number of approximately 32 and a hardnesstemperature (Tg) of 24° C. and a urethane polymer (b) has a viscosity(cP) of approximately 125 and a pH of 8+/−1 and is present in an amountof approximately 0.7% by weight and the alkali (c) is ammonium hydroxidethat is present in an amount of 0.06 to 0.6% by weight as needed toachieve a pH of the composition between 8 and 8.5.
 15. The method ofclaim 10 which further includes adding a dispersible pigment to thecomposition to achieve the desired color of paint.
 16. The method ofclaim 11 which further includes adding a dispersible pigment to thecomposition to achieve the desired color of paint.
 17. The method ofclaim 14 which further includes adding a dispersible pigment to thecomposition to achieve the desired color of paint.
 18. A system fortemporarily coating a surface of an article and rapidly removing thecoating which comprises: a. coating the surface of the article with adispersion of the coating composition of claim 1; and b. removing thecoating using a coating remover concentrate composition which comprisesfrom 1 to 5% by weight of ammonium hydroxide and 2 to 5% by weight ofalkali thickeners and the balance water which is brought into contactwith the coating and agitating the coating and washing the residue withwater.
 19. The composition of claim 6 to which reflective beads havebeen added to the coating as the coating is being applied to a surface.20. (canceled)
 21. A method for temporarily protecting the surface ofunpainted or painted articles which comprises coating the surface of thearticle with a composition of claim 1 and removing the coating with aremover which comprises from 0.2 to 5% by weight of alkali and thickenerwhich is brought into contact with the coating and agitated and allowedto set for a few minutes and then washed away with water.
 22. The methodof claim 21 in which the remover comprises from 1 to 5% by weight ofammonium hydroxide and 2 to 5% by weight of alkali thickeners and thebalance water.
 23. The method of claim 21 in which the remover comprisesa combination of dibasic esters and thickeners.
 24. A method fortemporarily protecting the surface of unpainted or painted articleswhich comprises coating the surface of the article with a composition ofclaim 1 and removing the coating with a remover which comprises anorganic solvent where the pH has been adjusted as necessary to removethe paint.